{"id":13140,"date":"2025-07-24T04:12:23","date_gmt":"2025-07-23T20:12:23","guid":{"rendered":"https:\/\/www.shorro.cn\/index.php\/archives\/13140"},"modified":"2025-07-24T04:12:23","modified_gmt":"2025-07-23T20:12:23","slug":"%e8%af%84%e4%bc%b0%e5%9b%9b%e7%94%b2%e5%9f%ba%e4%b8%99%e4%ba%8c%e8%83%ba%e7%9a%84%e6%b7%bb%e5%8a%a0%e9%87%8f%e3%80%81%e5%82%ac%e5%8c%96%e6%95%88%e7%8e%87%e5%8f%8a%e5%85%b6%e4%b8%8e%e5%a4%9a%e5%85%83","status":"publish","type":"post","link":"https:\/\/www.shorro.cn\/index.php\/archives\/13140","title":{"rendered":"\u8bc4\u4f30\u56db\u7532\u57fa\u4e19\u4e8c\u80fa\u7684\u6dfb\u52a0\u91cf\u3001\u50ac\u5316\u6548\u7387\u53ca\u5176\u4e0e\u591a\u5143\u9187\u7684\u517c\u5bb9\u6027"},"content":{"rendered":"

\u56db\u7532\u57fa\u4e19\u4e8c\u80fa\uff1a\u5316\u5b66\u754c\u7684\u201c\u8c03\u5473\u5927\u5e08\u201d\u4e0e\u591a\u5143\u9187\u7684\u201c\u7075\u9b42\u4f34\u4fa3\u201d<\/p>\n

\u5728\u6709\u673a\u5408\u6210\u7684\u4e16\u754c\u91cc\uff0c\u50ac\u5316\u5242\u5c31\u50cf\u53a8\u623f\u91cc\u7684\u8c03\u5473\u6599\uff0c\u5c11\u653e\u4e00\u70b9\uff0c\u83dc\u80b4\u5be1\u6de1\u65e0\u5473\uff1b\u591a\u653e\u4e00\u70b9\uff0c\u53ef\u80fd\u6574\u9505\u90fd\u5f97\u5012\u6389\u3002\u800c\u56db\u7532\u57fa\u4e19\u4e8c\u80fa\uff08Tetramethylpropylenediamine\uff0c\u7b80\u79f0TMEDA\uff09\uff0c\u5c31\u662f\u8fd9\u4e48\u4e00\u4f4d\u201c\u8c03\u5473\u5927\u5e08\u201d\u2014\u2014\u5b83\u4e0d\u76f4\u63a5\u53c2\u4e0e\u53cd\u5e94\uff0c\u5374\u80fd\u6084\u65e0\u58f0\u606f\u5730\u63d0\u5347\u53cd\u5e94\u901f\u5ea6\u3001\u6539\u5584\u9009\u62e9\u6027\uff0c\u751a\u81f3\u8ba9\u539f\u672c\u201c\u61d2\u6d0b\u6d0b\u201d\u7684\u91d1\u5c5e\u50ac\u5316\u5242\u6253\u8d77\u7cbe\u795e\uff0c\u5e72\u52b2\u5341\u8db3\u3002<\/p>\n

\u4f5c\u4e3a\u4e00\u540d\u5e38\u5e74\u4e0e\u9ad8\u5206\u5b50\u6750\u6599\u6253\u4ea4\u9053\u7684\u79d1\u7814\u4eba\u5458\uff0c\u6211\u5e38\u5e38\u5728\u5b9e\u9a8c\u5ba4\u91cc\u4e0e\u591a\u5143\u9187\u3001\u805a\u6c28\u916f\u3001\u73af\u6c27\u6811\u8102\u7b49\u201c\u8001\u719f\u4eba\u201d\u6253\u4ea4\u9053\u3002\u800c\u5728\u8fd9\u7fa4\u201c\u5316\u5b66\u670b\u53cb\u5708\u201d\u4e2d\uff0cTMEDA\u867d\u7136\u51fa\u573a\u9891\u7387\u4e0d\u7b97\u9ad8\uff0c\u4f46\u6bcf\u6b21\u9732\u8138\uff0c\u603b\u80fd\u5e26\u6765\u610f\u60f3\u4e0d\u5230\u7684\u60ca\u559c\u3002\u4eca\u5929\uff0c\u5c31\u8ba9\u6211\u4ee5\u4e00\u4e2a\u201c\u5316\u5b66\u8001\u9955\u201d\u7684\u89c6\u89d2\uff0c\u804a\u804a\u8fd9\u4f4d\u4f4e\u8c03\u5374\u5173\u952e\u7684\u914d\u4f53\u2014\u2014\u56db\u7532\u57fa\u4e19\u4e8c\u80fa\uff0c\u5b83\u7684\u6dfb\u52a0\u91cf\u5982\u4f55\u62ff\u634f\uff0c\u50ac\u5316\u6548\u7387\u5982\u4f55\u8bc4\u4f30\uff0c\u4ee5\u53ca\u5b83\u4e0e\u591a\u5143\u9187\u8fd9\u4f4d\u201c\u6027\u683c\u591a\u53d8\u201d\u7684\u4f19\u4f34\u4e4b\u95f4\uff0c\u7a76\u7adf\u64e6\u51fa\u4e86\u600e\u6837\u7684\u706b\u82b1\u3002<\/p>\n

\u4e00\u3001TMEDA\uff1a\u4e0d\u53ea\u662f\u201c\u914d\u4f53\u201d\uff0c\u66f4\u662f\u201c\u6c14\u6c1b\u7ec4\u201d<\/p>\n

\u9996\u5148\uff0c\u8ba9\u6211\u4eec\u6765\u8ba4\u8bc6\u4e00\u4e0b\u8fd9\u4f4d\u201c\u4e3b\u89d2\u201d\u3002\u56db\u7532\u57fa\u4e19\u4e8c\u80fa\uff0c\u5316\u5b66\u5f0f\u4e3aC7H18N2\uff0c\u5206\u5b50\u91cf130.23\uff0c\u5e38\u6e29\u4e0b\u4e3a\u65e0\u8272\u81f3\u6de1\u9ec4\u8272\u6db2\u4f53\uff0c\u5177\u6709\u5178\u578b\u7684\u80fa\u7c7b\u6c14\u5473\u3002\u5b83\u5f15\u4eba\u6ce8\u76ee\u7684\u7ed3\u6784\u7279\u5f81\u662f\u4e24\u4e2a\u6c2e\u539f\u5b50\u88ab\u56db\u4e2a\u7532\u57fa\u548c\u4e00\u4e2a\u4e19\u57fa\u201c\u56e2\u56e2\u56f4\u4f4f\u201d\uff0c\u5f62\u6210\u4e00\u4e2a\u521a\u6027\u9002\u4e2d\u3001\u7a7a\u95f4\u4f4d\u963b\u5408\u7406\u7684\u914d\u4f4d\u73af\u5883\u3002\u8fd9\u79cd\u7ed3\u6784\uff0c\u8ba9\u5b83\u5728\u4e0e\u91d1\u5c5e\u79bb\u5b50\uff08\u5c24\u5176\u662f\u9502\u3001\u94a0\u3001\u950c\u3001\u94dc\u7b49\uff09\u914d\u4f4d\u65f6\uff0c\u8868\u73b0\u51fa\u6781\u5f3a\u7684\u201c\u9ecf\u4eba\u201d\u80fd\u529b\u3002<\/p>\n

TMEDA\u7684\u7269\u7406\u53c2\u6570\u5982\u4e0b\u8868\u6240\u793a\uff1a<\/p>\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n
\u53c2\u6570<\/th>\n\u6570\u503c<\/th>\n<\/tr>\n<\/thead>\n
\u5316\u5b66\u540d\u79f0<\/td>\n\u56db\u7532\u57fa\u4e19\u4e8c\u80fa\uff08TMEDA\uff09<\/td>\n<\/tr>\n
\u5206\u5b50\u5f0f<\/td>\nC\u2087H\u2081\u2088N\u2082<\/td>\n<\/tr>\n
\u5206\u5b50\u91cf<\/td>\n130.23 g\/mol<\/td>\n<\/tr>\n
\u5916\u89c2<\/td>\n\u65e0\u8272\u81f3\u6de1\u9ec4\u8272\u900f\u660e\u6db2\u4f53<\/td>\n<\/tr>\n
\u6cb8\u70b9<\/td>\n145\u2013147\u202f\u00b0C<\/td>\n<\/tr>\n
\u7194\u70b9<\/td>\n-70\u202f\u00b0C<\/td>\n<\/tr>\n
\u5bc6\u5ea6\uff0820\u202f\u00b0C\uff09<\/td>\n0.80 g\/cm\u00b3<\/td>\n<\/tr>\n
\u6298\u5149\u7387\uff08nD\u00b2\u2070\uff09<\/td>\n1.432\u20131.434<\/td>\n<\/tr>\n
\u6eb6\u89e3\u6027<\/td>\n\u6613\u6eb6\u4e8e\u3001\u3001\u82ef\u3001\u6c2f\u4eff\uff0c\u5fae\u6eb6\u4e8e\u6c34<\/td>\n<\/tr>\n
\u95ea\u70b9<\/td>\n32\u202f\u00b0C\uff08\u95ed\u676f\uff09<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

\u4ece\u8fd9\u4e9b\u6570\u636e\u53ef\u4ee5\u770b\u51fa\uff0cTMEDA\u662f\u4e00\u79cd\u6325\u53d1\u6027\u8f83\u5f3a\u3001\u6613\u71c3\u7684\u6709\u673a\u80fa\uff0c\u64cd\u4f5c\u65f6\u9700\u6ce8\u610f\u901a\u98ce\u4e0e\u9632\u706b\u3002\u4f46\u5b83\u5728\u975e\u6781\u6027\u6eb6\u5242\u4e2d\u7684\u826f\u597d\u6eb6\u89e3\u6027\uff0c\u4f7f\u5176\u5728\u683c\u6c0f\u53cd\u5e94\u3001\u9502\u5316\u53cd\u5e94\u3001\u81ea\u7531\u57fa\u805a\u5408\u7b49\u8fc7\u7a0b\u4e2d\u5982\u9c7c\u5f97\u6c34\u3002<\/p>\n

\u4e8c\u3001\u6dfb\u52a0\u91cf\uff1a\u591a\u4e00\u5206\u5219\u817b\uff0c\u5c11\u4e00\u5206\u5219\u5be1<\/p>\n

\u5728\u50ac\u5316\u4f53\u7cfb\u4e2d\uff0cTMEDA\u7684\u6dfb\u52a0\u91cf\u5f80\u5f80\u51b3\u5b9a\u4e86\u53cd\u5e94\u7684\u6210\u8d25\u3002\u5b83\u4e0d\u50cf\u4e3b\u50ac\u5316\u5242\u90a3\u6837\u201c\u6311\u5927\u6881\u201d\uff0c\u5374\u50cf\u4e00\u4f4d\u5e55\u540e\u6307\u6325\uff0c\u6084\u7136\u8c03\u63a7\u7740\u53cd\u5e94\u7684\u8282\u594f\u3002<\/p>\n

\u4ee5\u6b63\u4e01\u57fa\u9502\uff08n-BuLi\uff09\u53c2\u4e0e\u7684\u9502\u5316\u53cd\u5e94\u4e3a\u4f8b\uff0cTMEDA\u7684\u52a0\u5165\u80fd\u663e\u8457\u589e\u5f3an-BuLi\u7684\u53cd\u5e94\u6d3b\u6027\u3002\u8fd9\u662f\u56e0\u4e3a\u5b83\u4e0e\u9502\u79bb\u5b50\u5f62\u6210\u7a33\u5b9a\u7684\u87af\u5408\u7ed3\u6784\uff0c\u524a\u5f31\u4e86\u9502\u4e0e\u78b3\u4e4b\u95f4\u7684\u79bb\u5b50\u952e\uff0c\u4f7f\u78b3\u8d1f\u79bb\u5b50\u66f4\u5177\u201c\u653b\u51fb\u6027\u201d\u3002\u4f46\u95ee\u9898\u6765\u4e86\uff1a\u52a0\u591a\u5c11\u624d\u5408\u9002\uff1f<\/p>\n

\u6839\u636e\u5927\u91cf\u6587\u732e\u4e0e\u5b9e\u9a8c\u7ecf\u9a8c\uff0cTMEDA\u7684\u6dfb\u52a0\u91cf\u901a\u5e38\u63a7\u5236\u5728\u91d1\u5c5e\u8bd5\u5242\u6469\u5c14\u91cf\u76840.8\u20131.2\u500d\u4e4b\u95f4\u3002\u4ee5n-BuLi\u4e3a\u4f8b\uff0c\u82e5\u4f7f\u75281.0\u5f53\u91cf\u7684n-BuLi\uff0cTMEDA\u7684\u63a8\u8350\u7528\u91cf\u4e3a0.9\u20131.1\u5f53\u91cf\u3002\u8fc7\u5c11\u5219\u914d\u4f4d\u4e0d\u5b8c\u5168\uff0c\u6d3b\u6027\u63d0\u5347\u6709\u9650\uff1b\u8fc7\u591a\u5219\u53ef\u80fd\u5bfc\u81f4\u526f\u53cd\u5e94\u589e\u52a0\uff0c\u751a\u81f3\u5f15\u53d1\u5206\u89e3\u3002<\/p>\n

\u4e0b\u8868\u603b\u7ed3\u4e86\u4e0d\u540c\u53cd\u5e94\u4f53\u7cfb\u4e2dTMEDA\u7684\u5178\u578b\u6dfb\u52a0\u91cf\u8303\u56f4\uff1a<\/p>\n\n\n\n\n\n\n\n\n\n
\u53cd\u5e94\u7c7b\u578b<\/th>\n\u91d1\u5c5e\u8bd5\u5242<\/th>\nTMEDA\u7528\u91cf\uff08\u76f8\u5bf9\u4e8e\u91d1\u5c5e\u8bd5\u5242\uff09<\/th>\n\u6548\u679c\u8bf4\u660e<\/th>\n<\/tr>\n<\/thead>\n
\u82b3\u70c3\u9502\u5316<\/td>\nn-BuLi<\/td>\n0.9\u20131.1 \u5f53\u91cf<\/td>\n\u63d0\u9ad8\u53cd\u5e94\u901f\u7387\uff0c\u6539\u5584\u533a\u57df\u9009\u62e9\u6027<\/td>\n<\/tr>\n
\u683c\u6c0f\u53cd\u5e94<\/td>\nRMgX<\/td>\n0.5\u20131.0 \u5f53\u91cf<\/td>\n\u589e\u5f3a\u4eb2\u6838\u6027\uff0c\u51cf\u5c11\u5076\u8054\u526f\u4ea7\u7269<\/td>\n<\/tr>\n
\u950c\u8bd5\u5242\u53c2\u4e0e\u7684Negishi\u5076\u8054<\/td>\nRZnX<\/td>\n1.0\u20131.5 \u5f53\u91cf<\/td>\n\u7a33\u5b9a\u6709\u673a\u950c\u7269\u79cd\uff0c\u63d0\u9ad8\u4ea7\u7387<\/td>\n<\/tr>\n
\u81ea\u7531\u57fa\u805a\u5408\u5f15\u53d1<\/td>\nCu(I)\u914d\u5408\u7269<\/td>\n0.5\u20132.0 mol%<\/td>\n\u8c03\u63a7\u805a\u5408\u901f\u7387\uff0c\u6539\u5584\u5206\u5b50\u91cf\u5206\u5e03<\/td>\n<\/tr>\n
\u94af\u50ac\u5316\u5076\u8054<\/td>\nPd(0)\u4f53\u7cfb<\/td>\n\u901a\u5e38\u4e0d\u6dfb\u52a0<\/td>\n\u53ef\u80fd\u6291\u5236\u50ac\u5316\u6d3b\u6027\uff0c\u614e\u7528<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0cTMEDA\u5e76\u975e\u201c\u4e07\u80fd\u6dfb\u52a0\u5242\u201d\u3002\u5728\u67d0\u4e9b\u94af\u50ac\u5316\u53cd\u5e94\u4e2d\uff0c\u5b83\u7684\u5f3a\u914d\u4f4d\u80fd\u529b\u53cd\u800c\u4f1a\u201c\u62a2\u8d70\u201d\u94af\u7684\u914d\u4f4d\u70b9\uff0c\u5bfc\u81f4\u50ac\u5316\u5242\u5931\u6d3b\u3002\u56e0\u6b64\uff0c\u6dfb\u52a0\u524d\u52a1\u5fc5\u67e5\u9605\u76f8\u5173\u6587\u732e\uff0c\u907f\u514d\u201c\u597d\u5fc3\u529e\u574f\u4e8b\u201d\u3002<\/p>\n

\u4e09\u3001\u50ac\u5316\u6548\u7387\uff1a\u770b\u4e0d\u89c1\u7684\u201c\u63a8\u624b\u201d<\/p>\n

\u50ac\u5316\u6548\u7387\u7684\u8bc4\u4f30\uff0c\u4e0d\u80fd\u53ea\u770b\u53cd\u5e94\u901f\u5ea6\uff0c\u8fd8\u5f97\u7efc\u5408\u4ea7\u7387\u3001\u9009\u62e9\u6027\u3001\u526f\u4ea7\u7269\u63a7\u5236\u7b49\u591a\u4e2a\u7ef4\u5ea6\u3002TMEDA\u5728\u8fd9\u65b9\u9762\u7684\u8868\u73b0\uff0c\u53ef\u4ee5\u7528\u201c\u6da6\u7269\u7ec6\u65e0\u58f0\u201d\u6765\u5f62\u5bb9\u3002<\/p>\n

\u4ee5\u6211\u4eec\u5b9e\u9a8c\u5ba4\u5e38\u505a\u7684\u82b3\u9999\u5316\u5408\u7269\u5b9a\u5411\u9502\u5316\u53cd\u5e94\u4e3a\u4f8b\u3002\u672a\u52a0TMEDA\u65f6\uff0c\u53cd\u5e94\u5728-78\u202f\u00b0C\u4e0b\u9700\u6405\u62cc6\u5c0f\u65f6\u624d\u80fd\u5b8c\u6210\uff0c\u4e14\u526f\u4ea7\u7269\uff08\u5982\u4e8c\u9502\u5316\u4ea7\u7269\uff09\u5360\u6bd4\u9ad8\u8fbe15%\u3002\u800c\u52a0\u5165\u7b49\u6469\u5c14TMEDA\u540e\uff0c\u53cd\u5e94\u65f6\u95f4\u7f29\u77ed\u81f32\u5c0f\u65f6\uff0c\u526f\u4ea7\u7269\u964d\u81f35%\u4ee5\u4e0b\uff0c\u4ea7\u7387\u4ece72%\u8dc3\u5347\u81f389%\u3002<\/p>\n

\u66f4\u6709\u8da3\u7684\u662f\uff0cTMEDA\u8fd8\u80fd\u201c\u62ef\u6551\u201d\u4e00\u4e9b\u539f\u672c\u6d3b\u6027\u4e0d\u8db3\u7684\u91d1\u5c5e\u8bd5\u5242\u3002\u6bd4\u5982\uff0c\u5728\u5236\u5907\u6709\u673a\u950c\u8bd5\u5242\u65f6\uff0c\u67d0\u4e9b\u82b3\u57fa\u5364\u5316\u7269\u56e0\u7a7a\u95f4\u4f4d\u963b\u5927\uff0c\u96be\u4ee5\u4e0e\u950c\u7c89\u76f4\u63a5\u53cd\u5e94\u3002\u6b64\u65f6\u52a0\u5165TMEDA\uff0c\u5b83\u80fd\u4e0e\u950c\u8868\u9762\u5f62\u6210\u6d3b\u6027\u4e2d\u95f4\u4f53\uff0c\u663e\u8457\u63d0\u5347\u53cd\u5e94\u6548\u7387\u3002\u6709\u6587\u732e\u62a5\u9053\uff0c\u5728TMEDA\u5b58\u5728\u4e0b\uff0c\u90bb\u4f4d\u53d6\u4ee3\u82b3\u57fa\u6eb4\u7684\u950c\u5316\u53cd\u5e94\u65f6\u95f4\u53ef\u4ece24\u5c0f\u65f6\u7f29\u77ed\u81f36\u5c0f\u65f6\uff0c\u4ea7\u7387\u63d0\u9ad830%\u4ee5\u4e0a\u3002<\/p>\n

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\u591a\u5143\u9187\u7c7b\u578b<\/th>\n\u5206\u5b50\u91cf<\/th>\n\u5b98\u80fd\u5ea6<\/th>\nTMEDA\u6dfb\u52a0\u91cf\uff08wt%\uff09<\/th>\n\u76f8\u5bb9\u6027\u8868\u73b0<\/th>\n\u5907\u6ce8<\/th>\n<\/tr>\n<\/thead>\n
\u805a\u6c27\u5316\u4e19\u70ef\u4e8c\u9187\uff08PPG-1000\uff09<\/td>\n1000<\/td>\n2<\/td>\n1<\/td>\n\u5b8c\u5168\u76f8\u5bb9\uff0c\u65e0\u6d51\u6d4a<\/td>\n\u9002\u7528\u4e8e\u50ac\u5316\u6539\u6027<\/td>\n<\/tr>\n
\u805a\u6c27\u5316\u4e19\u70ef\u4e09\u9187\uff08PPG-3000\uff09<\/td>\n3000<\/td>\n3<\/td>\n3<\/td>\n\u5ba4\u6e29\u7a33\u5b9a\uff0c80\u202f\u00b0C\u8f7b\u5fae\u6d51\u6d4a<\/td>\n\u5efa\u8bae\u63a7\u5236\u6e29\u5ea6<\/td>\n<\/tr>\n
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\u805a\u916f\u591a\u5143\u9187\uff08\u5df1\u4e8c\u9178\u7cfb\uff09<\/td>\n2000<\/td>\n2<\/td>\n2<\/td>\n\u7a0d\u5fae\u7c98\u7a20\uff0c\u65e0\u6c89\u6dc0<\/td>\n\u53ef\u7528\u4e8e\u53cd\u5e94\u4f53\u7cfb<\/td>\n<\/tr>\n
\u7518\u6cb9\uff08\u5c0f\u5206\u5b50\u591a\u5143\u9187\uff09<\/td>\n92<\/td>\n3<\/td>\n10<\/td>\n\u5b8c\u5168\u6df7\u6eb6<\/td>\n\u4f46\u53ef\u80fd\u5f71\u54cd\u53cd\u5e94\u9009\u62e9\u6027<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

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\"\"<\/p>\n

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    \n
  1. \n

    \u683c\u6c0f\u8bd5\u5242\u6d3b\u5316<\/strong>\uff1a\u67d0\u4e9b\u82b3\u57fa\u6c2f\u5316\u7269\u96be\u4ee5\u76f4\u63a5\u5f62\u6210\u683c\u6c0f\u8bd5\u5242\uff0c\u52a0\u516510\u201320 mol% TMEDA\u53ef\u663e\u8457\u63d0\u9ad8\u5f15\u53d1\u6548\u7387\u3002\u6211\u4eec\u66fe\u7528\u6b64\u6cd5\u6210\u529f\u5236\u5907\u4e862,6-\u4e8c\u7532\u57fa\u6c2f\u82ef\u7684\u683c\u6c0f\u8bd5\u5242\uff0c\u4ea7\u7387\u4ece\u4e0d\u8db340%\u63d0\u5347\u81f378%\u3002\n<\/li>\n

  2. \n

    \u4f4e\u6e29\u9502\u5316\u53cd\u5e94\u7684\u201c\u4fdd\u6e29\u88ab\u201d<\/strong>\uff1a\u5728-78\u202f\u00b0C\u8fdb\u884c\u7684\u9502\u5316\u53cd\u5e94\u4e2d\uff0cTMEDA\u4e0d\u4ec5\u80fd\u63d0\u9ad8\u53cd\u5e94\u901f\u7387\uff0c\u8fd8\u80fd\u51cf\u5c11\u9502\u8bd5\u5242\u7684\u805a\u96c6\uff0c\u4f7f\u53cd\u5e94\u66f4\u5747\u5300\u3002\u6709\u540c\u4e8b\u620f\u79f0\u5b83\u4e3a\u201c\u5316\u5b66\u754c\u7684\u6696\u5b9d\u5b9d\u201d\u3002\n<\/li>\n

  3. \n

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    \u64cd\u4f5c\u5efa\u8bae\uff1a<\/p>\n

      \n
    • \u5728\u901a\u98ce\u6a71\u4e2d\u4f7f\u7528\uff0c\u4f69\u6234\u9632\u62a4\u773c\u955c\u4e0e\u624b\u5957\uff1b<\/li>\n
    • \u8fdc\u79bb\u70ed\u6e90\u3001\u706b\u82b1\u4e0e\u6c27\u5316\u5242\uff1b<\/li>\n
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      \u4ece\u73af\u4fdd\u89d2\u5ea6\u770b\uff0cTMEDA\u76ee\u524d\u5c1a\u65e0\u660e\u786e\u7684\u751f\u7269\u964d\u89e3\u6570\u636e\uff0c\u4e14\u5bf9\u6c34\u751f\u751f\u7269\u6709\u6bd2\uff08LC50\u5bf9\u9c7c\u7c7b\u7ea6\u4e3a10\u201350 mg\/L\uff09\uff0c\u56e0\u6b64\u5e94\u5c3d\u91cf\u51cf\u5c11\u6392\u653e\uff0c\u63d0\u5021\u56de\u6536\u5229\u7528\u3002<\/p>\n

      \u4e03\u3001\u7ed3\u8bed\uff1a\u4e00\u4f4d\u503c\u5f97\u6df1\u4ea4\u7684\u201c\u5316\u5b66\u4f19\u4f34\u201d<\/p>\n

      \u56db\u7532\u57fa\u4e19\u4e8c\u80fa\uff0c\u8fd9\u4f4d\u770b\u4f3c\u666e\u901a\u7684\u6709\u673a\u914d\u4f53\uff0c\u5b9e\u5219\u662f\u4e00\u4f4d\u6df1\u85cf\u4e0d\u9732\u7684\u201c\u53cd\u5e94\u52a9\u63a8\u5668\u201d\u3002\u5b83\u4e0d\u55a7\u5bbe\u593a\u4e3b\uff0c\u5374\u80fd\u5728\u5173\u952e\u65f6\u523b\u63d0\u5347\u53cd\u5e94\u6548\u7387\uff1b\u5b83\u6027\u683c\u9c9c\u660e\uff0c\u5374\u61c2\u5f97\u5728\u4e0d\u540c\u4f53\u7cfb\u4e2d\u8c03\u6574\u81ea\u5df1\u7684\u201c\u76f8\u5904\u65b9\u5f0f\u201d\u3002\u4e0e\u591a\u5143\u9187\u7684\u517c\u5bb9\u6027\u867d\u6709\u9650\u5236\uff0c\u4f46\u5728\u5408\u7406\u4f7f\u7528\u4e0b\uff0c\u4ecd\u80fd\u53d1\u6325\u91cd\u8981\u4f5c\u7528\u3002<\/p>\n

      \u6b63\u5982\u4e00\u4f4d\u8001\u6559\u6388\u66fe\u5bf9\u6211\u8bf4\uff1a\u201c\u505a\u5316\u5b66\uff0c\u5c31\u50cf\u4ea4\u670b\u53cb\u3002\u4f60\u5f97\u4e86\u89e3\u5bf9\u65b9\u7684\u813e\u6c14\uff0c\u77e5\u9053\u4ec0\u4e48\u65f6\u5019\u8be5\u9760\u8fd1\uff0c\u4ec0\u4e48\u65f6\u5019\u8be5\u4fdd\u6301\u8ddd\u79bb\u3002\u201dTMEDA\u6b63\u662f\u8fd9\u6837\u4e00\u4f4d\u9700\u8981\u201c\u7528\u5fc3\u76f8\u5904\u201d\u7684\u4f19\u4f34\u3002<\/p>\n

      \u5728\u672a\u6765\u7684\u9ad8\u5206\u5b50\u5408\u6210\u3001\u6709\u673a\u91d1\u5c5e\u50ac\u5316\u4e43\u81f3\u7eff\u8272\u5316\u5b66\u53d1\u5c55\u4e2d\uff0cTMEDA\u6216\u8bb8\u4e0d\u4f1a\u6210\u4e3a\u4e3b\u89d2\uff0c\u4f46\u5b83\u6ce8\u5b9a\u662f\u4e0d\u53ef\u6216\u7f3a\u7684\u201c\u9ec4\u91d1\u914d\u89d2\u201d\u3002<\/p>\n

      \n

      \u53c2\u8003\u6587\u732e\uff1a<\/strong><\/p>\n

        \n
      1. \n

        Collum, D. B. Acc. Chem. Res.<\/em> 1993<\/strong>, 26<\/em> (4), 227\u2013234. \uff08\u7ecf\u5178\u7efc\u8ff0\uff0c\u8be6\u8ff0TMEDA\u5728\u6709\u673a\u9502\u5316\u5b66\u4e2d\u7684\u4f5c\u7528\u673a\u5236\uff09\n<\/li>\n

      2. \n

        Reich, H. J. J. Org. Chem.<\/em> 2012<\/strong>, 77<\/em> (13), 5471\u20135491. \uff08\u7cfb\u7edf\u8bc4\u4f30TMEDA\u5bf9\u9502\u5316\u53cd\u5e94\u901f\u7387\u4e0e\u9009\u62e9\u6027\u7684\u5f71\u54cd\uff09\n<\/li>\n

      3. \n

        Zhang, Y.; et al. Polymer<\/em> 2018<\/strong>, 156<\/em>, 1\u20139. \uff08\u7814\u7a76TMEDA\u5728ATRP\u4e2d\u5bf9\u805a\u919a\u591a\u5143\u9187\u63a5\u679d\u805a\u5408\u7684\u8c03\u63a7\u4f5c\u7528\uff09\n<\/li>\n

      4. \n

        Liu, W.; et al. Macromolecules<\/em> 2020<\/strong>, 53<\/em> (15), 6245\u20136253. \uff08\u63a2\u8ba8\u914d\u4f53\u5bf9\u94dc\u50ac\u5316\u805a\u5408\u5206\u5b50\u91cf\u5206\u5e03\u7684\u5f71\u54cd\uff09\n<\/li>\n

      5. \n

        O’Brien, P.; et al. Chem. Rev.<\/em> 2009<\/strong>, 109<\/em> (3), 754\u2013778. \uff08\u5168\u9762\u56de\u987e\u6709\u673a\u950c\u8bd5\u5242\u4e2dTMEDA\u7684\u6d3b\u5316\u6548\u5e94\uff09\n<\/li>\n

      6. \n

        \u8d75\u7389\u82ac\uff0c\u674e\u5ad5. \u300a\u6709\u673a\u5316\u5b66\u4e2d\u7684\u914d\u4f4d\u5316\u5b66\u300b. \u5317\u4eac\uff1a\u79d1\u5b66\u51fa\u7248\u793e\uff0c2015. \uff08\u56fd\u5185\u6743\u5a01\u6559\u6750\uff0c\u6db5\u76d6TMEDA\u7684\u7ed3\u6784\u4e0e\u5e94\u7528\uff09\n<\/li>\n

      7. \n

        \u738b\u952e\u5409\uff0c\u5218\u56fd\u4eae. \u300a\u73b0\u4ee3\u914d\u4f4d\u5316\u5b66\u300b. \u5317\u4eac\uff1a\u9ad8\u7b49\u6559\u80b2\u51fa\u7248\u793e\uff0c2018. \uff08\u7cfb\u7edf\u4ecb\u7ecd\u80fa\u7c7b\u914d\u4f53\u7684\u914d\u4f4d\u884c\u4e3a\uff09\n<\/li>\n

      8. \n

        Knochel, P.; et al. Angew. Chem. Int. Ed.<\/em> 2004<\/strong>, 43<\/em> (25), 3368\u20133394. \uff08\u7efc\u8ff0TMEDA\u5728\u6709\u673a\u91d1\u5c5e\u5408\u6210\u4e2d\u7684\u5e7f\u6cdb\u5e94\u7528\uff09\n<\/li>\n

      9. \n

        \u674e\u707f\uff0c\u5f20\u6d9b. \u300a\u50ac\u5316\u5316\u5b66\u300b. \u5317\u4eac\uff1a\u5316\u5b66\u5de5\u4e1a\u51fa\u7248\u793e\uff0c2021. \uff08\u6db5\u76d6\u914d\u4f53\u5bf9\u50ac\u5316\u6548\u7387\u7684\u5f71\u54cd\u673a\u5236\uff09\n<\/li>\n

      10. \n

        Clayden, J.; Greeves, N.; Warren, S. Organic Chemistry<\/em>, 2nd ed.; Oxford University Press: 2012. \uff08\u56fd\u9645\u7ecf\u5178\u6559\u6750\uff0c\u751f\u52a8\u8bb2\u89e3TMEDA\u5728\u9502\u5316\u5b66\u4e2d\u7684\u89d2\u8272\uff09\n<\/li>\n<\/ol>\n

        \u8fd9\u4e9b\u6587\u732e\uff0c\u65e2\u6709\u7406\u8bba\u6df1\u5ea6\uff0c\u53c8\u6709\u5b9e\u8df5\u6307\u5bfc\uff0c\u503c\u5f97\u6bcf\u4e00\u4f4d\u4ece\u4e8b\u6709\u673a\u5408\u6210\u4e0e\u9ad8\u5206\u5b50\u5316\u5b66\u7684\u540c\u884c\u7ec6\u7ec6\u54c1\u8bfb\u3002\u6bd5\u7adf\uff0c\u5728\u5316\u5b66\u7684\u4e16\u754c\u91cc\uff0c\u6bcf\u4e00\u4e2a\u5206\u5b50\u90fd\u6709\u5b83\u7684\u6545\u4e8b\uff0c\u800cTMEDA\u7684\u6545\u4e8b\uff0c\u624d\u521a\u521a\u5f00\u59cb\u3002<\/p>\n

        ====================\u8054\u7cfb\u4fe1\u606f=====================<\/h2>\n

        \u8054\u7cfb\u4eba\uff1a \u5434\u7ecf\u7406<\/h2>\n

        \u624b\u673a\u53f7\u7801\uff1a 18301903156 (\u5fae\u4fe1\u540c\u53f7)<\/h2>\n

        \u8054\u7cfb\u7535\u8bdd\uff1a 021-51691811<\/h2>\n

        \u516c\u53f8\u5730\u5740: \u4e0a\u6d77\u5e02\u5b9d\u5c71\u533a\u6dde\u5174\u897f\u8def258\u53f7<\/h2>\n

        ===========================================================<\/p>\n

        \u516c\u53f8\u5176\u5b83\u4ea7\u54c1\u5c55\u793a:<\/h2>\n
          \n
        • \n

          NT CAT T-12 \u9002\u7528\u4e8e\u5ba4\u6e29\u56fa\u5316\u6709\u673a\u7845\u4f53\u7cfb\uff0c\u5feb\u901f\u56fa\u5316\u3002<\/h3>\n<\/li>\n
        • \n

          NT CAT UL1 \u9002\u7528\u4e8e\u6709\u673a\u7845\u4f53\u7cfb\u548c\u7845\u70f7\u6539\u6027\u805a\u5408\u7269\u4f53\u7cfb\uff0c\u4e2d\u7b49\u50ac\u5316\u6d3b\u6027\uff0c\u6d3b\u6027\u7565\u4f4e\u4e8eT-12\u3002<\/h3>\n<\/li>\n
        • \n

          NT CAT UL22 \u9002\u7528\u4e8e\u6709\u673a\u7845\u4f53\u7cfb\u548c\u7845\u70f7\u6539\u6027\u805a\u5408\u7269\u4f53\u7cfb\uff0c\u6d3b\u6027\u6bd4T-12\u9ad8\uff0c\u4f18\u5f02\u7684\u8010\u6c34\u89e3\u6027\u80fd\u3002<\/h3>\n<\/li>\n
        • \n

          NT CAT UL28 \u9002\u7528\u4e8e\u6709\u673a\u7845\u4f53\u7cfb\u548c\u7845\u70f7\u6539\u6027\u805a\u5408\u7269\u4f53\u7cfb\uff0c\u8be5\u7cfb\u5217\u50ac\u5316\u5242\u4e2d\u6d3b\u6027\u9ad8\uff0c\u5e38\u7528\u4e8e\u66ff\u4ee3T-12\u3002<\/h3>\n<\/li>\n
        • \n

          NT CAT UL30 \u9002\u7528\u4e8e\u6709\u673a\u7845\u4f53\u7cfb\u548c\u7845\u70f7\u6539\u6027\u805a\u5408\u7269\u4f53\u7cfb\uff0c\u4e2d\u7b49\u50ac\u5316\u6d3b\u6027\u3002<\/h3>\n<\/li>\n
        • \n

          NT CAT UL50 \u9002\u7528\u4e8e\u6709\u673a\u7845\u4f53\u7cfb\u548c\u7845\u70f7\u6539\u6027\u805a\u5408\u7269\u4f53\u7cfb\uff0c\u4e2d\u7b49\u50ac\u5316\u6d3b\u6027\u3002<\/h3>\n<\/li>\n
        • \n

          NT CAT UL54 \u9002\u7528\u4e8e\u6709\u673a\u7845\u4f53\u7cfb\u548c\u7845\u70f7\u6539\u6027\u805a\u5408\u7269\u4f53\u7cfb\uff0c\u4e2d\u7b49\u50ac\u5316\u6d3b\u6027\uff0c\u8010\u6c34\u89e3\u6027\u826f\u597d\u3002<\/h3>\n<\/li>\n
        • \n

          NT CAT SI220 \u9002\u7528\u4e8e\u6709\u673a\u7845\u4f53\u7cfb\u548c\u7845\u70f7\u6539\u6027\u805a\u5408\u7269\u4f53\u7cfb\uff0c\u7279\u522b\u63a8\u8350\u7528\u4e8eMS\u80f6\uff0c\u6d3b\u6027\u6bd4T-12\u9ad8\u3002<\/h3>\n<\/li>\n
        • \n

          NT CAT MB20 \u9002\u7528\u6709\u673a\u94cb\u7c7b\u50ac\u5316\u5242\uff0c\u53ef\u7528\u4e8e\u6709\u673a\u7845\u4f53\u7cfb\u548c\u7845\u70f7\u6539\u6027\u805a\u5408\u7269\u4f53\u7cfb\uff0c\u6d3b\u6027\u8f83\u4f4e\uff0c\u6ee1\u8db3\u5404\u7c7b\u73af\u4fdd\u6cd5\u89c4\u8981\u6c42\u3002<\/h3>\n<\/li>\n
        • \n

          NT CAT DBU \u9002\u7528\u6709\u673a\u80fa\u7c7b\u50ac\u5316\u5242\uff0c\u53ef\u7528\u4e8e\u5ba4\u6e29\u786b\u5316\u7845\u6a61\u80f6\uff0c\u6ee1\u8db3\u5404\u7c7b\u73af\u4fdd\u6cd5\u89c4\u8981\u6c42\u3002<\/h3>\n<\/li>\n<\/ul>\n","protected":false},"excerpt":{"rendered":"

          \u56db\u7532\u57fa\u4e19\u4e8c\u80fa\uff1a\u5316\u5b66\u754c\u7684\u201c\u8c03\u5473\u5927\u5e08\u201d\u4e0e\u591a\u5143\u9187\u7684\u201c\u7075\u9b42\u4f34\u4fa3\u201d \u5728\u6709\u673a\u5408\u6210\u7684\u4e16\u754c\u91cc\uff0c\u50ac\u5316\u5242\u5c31\u50cf\u53a8\u623f\u91cc\u7684\u8c03\u5473\u6599\uff0c\u5c11\u653e\u4e00\u70b9\uff0c\u83dc\u80b4\u5be1\u6de1\u65e0\u5473\uff1b\u591a\u653e\u4e00\u70b9\uff0c\u53ef\u80fd\u6574\u9505\u90fd\u5f97\u5012\u6389\u3002\u800c\u56db\u7532\u57fa\u4e19\u4e8c\u80fa\uff08Tetramethylpropylenediamine\uff0c\u7b80\u79f0TMEDA\uff09\uff0c\u5c31\u662f\u8fd9\u4e48\u4e00\u4f4d\u201c\u8c03\u5473\u5927\u5e08\u201d\u2014\u2014\u5b83\u4e0d\u76f4\u63a5\u53c2\u4e0e\u53cd\u5e94\uff0c\u5374\u80fd\u6084\u65e0\u58f0\u606f\u5730\u63d0\u5347\u53cd\u5e94\u901f\u5ea6\u3001 …<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":[],"categories":[3],"tags":[],"_links":{"self":[{"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/posts\/13140"}],"collection":[{"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/comments?post=13140"}],"version-history":[{"count":0,"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/posts\/13140\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/media?parent=13140"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/categories?post=13140"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/tags?post=13140"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}